Thermodynamic Processes
Class 11 Physics notes covering Isothermal, Adiabatic, Isochoric and Isobaric Processes, PV Diagrams, Work Done, Process Comparison, Numericals and PYQs.
Thermodynamic processes describe how a gas moves from one equilibrium state to another. The four standard processes are isothermal, adiabatic, isochoric and isobaric. Each process has a fixed condition, a characteristic P-V graph, a particular work formula and a different heat-internal-energy relation.
Introduction
A thermodynamic process is the path followed by a system when it changes from one state to another.
For a fixed amount of gas, the state is commonly described by pressure, volume and temperature. A process tells us how these quantities change. The same initial and final states may be connected by different paths, and the work done and heat exchanged may be different for different paths. This is why P-V diagrams are central in thermodynamics.
In exams, do not start with a formula blindly. First identify the constant quantity: temperature, heat, volume or pressure. Then choose the correct process formula. Isothermal means T constant. Adiabatic means Q = 0. Isochoric means V constant. Isobaric means P constant.
Path Matters
Work and heat depend on the path. P-V graph shape is therefore part of the physics, not decoration.
State Function
Internal energy change for an ideal gas depends only on temperature change, not on the chosen path.
Exam Habit
Mark the process condition before substitution: T constant, Q zero, V constant or P constant.
Isothermal Process
For an ideal gas in an isothermal process, temperature remains constant. Since internal energy of an ideal gas depends only on temperature, ΔU = 0. Heat supplied during isothermal expansion is completely converted into work done by the gas. The process must be slow enough for heat exchange with surroundings to maintain temperature.
Physical and Molecular Meaning
At molecular level, the process condition controls how molecular speed, collision rate and wall pressure change. In isothermal process, the chosen constraint decides whether heat exchange, work transfer or internal energy change dominates the process.
Real-Life Examples
Examples include slow expansion of gas in a cylinder kept in contact with a heat reservoir and slow compression where heat is removed continuously.
Exam Perspective
- Always write the defining condition first.
- Draw the P-V graph shape before solving graph-based questions.
- Check whether work is zero, positive or negative from volume change.
- For ideal gas, connect internal energy change with temperature change.
Common Mistakes and Memory Tricks
Do not confuse process names. Isothermal has constant temperature, while adiabatic has zero heat exchange. Isochoric has zero work, while isobaric uses W = PΔV. The memory trick is: thermal relates to temperature, adiabatic blocks heat, choric relates to volume space, and baric relates to pressure.
Adiabatic Process
In an adiabatic process, no heat enters or leaves the system. Work is done at the cost of internal energy during expansion, so temperature falls. During adiabatic compression, work is done on the gas and temperature rises. The adiabatic P-V curve is steeper than the isothermal curve because pressure changes more rapidly with volume.
Physical and Molecular Meaning
At molecular level, the process condition controls how molecular speed, collision rate and wall pressure change. In adiabatic process, the chosen constraint decides whether heat exchange, work transfer or internal energy change dominates the process.
Real-Life Examples
Examples include rapid compression in a bicycle pump, diesel engine compression and fast expansion of gas from a nozzle.
Exam Perspective
- Always write the defining condition first.
- Draw the P-V graph shape before solving graph-based questions.
- Check whether work is zero, positive or negative from volume change.
- For ideal gas, connect internal energy change with temperature change.
Common Mistakes and Memory Tricks
Do not confuse process names. Isothermal has constant temperature, while adiabatic has zero heat exchange. Isochoric has zero work, while isobaric uses W = PΔV. The memory trick is: thermal relates to temperature, adiabatic blocks heat, choric relates to volume space, and baric relates to pressure.
Isochoric Process
In an isochoric process, the volume remains constant, so the boundary does not move and no P-V work is done. Heat supplied changes internal energy directly. Pressure and temperature change together for an ideal gas at constant volume.
Physical and Molecular Meaning
At molecular level, the process condition controls how molecular speed, collision rate and wall pressure change. In isochoric process, the chosen constraint decides whether heat exchange, work transfer or internal energy change dominates the process.
Real-Life Examples
Examples include heating gas in a rigid sealed container or pressure rise in a closed pressure cooker before steam release.
Exam Perspective
- Always write the defining condition first.
- Draw the P-V graph shape before solving graph-based questions.
- Check whether work is zero, positive or negative from volume change.
- For ideal gas, connect internal energy change with temperature change.
Common Mistakes and Memory Tricks
Do not confuse process names. Isothermal has constant temperature, while adiabatic has zero heat exchange. Isochoric has zero work, while isobaric uses W = PΔV. The memory trick is: thermal relates to temperature, adiabatic blocks heat, choric relates to volume space, and baric relates to pressure.
Isobaric Process
In an isobaric process, pressure remains constant while volume and temperature may change. Heat supplied is used partly to increase internal energy and partly to do expansion work. On a P-V graph, the isobaric process is a horizontal line.
Physical and Molecular Meaning
At molecular level, the process condition controls how molecular speed, collision rate and wall pressure change. In isobaric process, the chosen constraint decides whether heat exchange, work transfer or internal energy change dominates the process.
Real-Life Examples
Examples include gas expanding under a freely moving piston carrying constant load.
Exam Perspective
- Always write the defining condition first.
- Draw the P-V graph shape before solving graph-based questions.
- Check whether work is zero, positive or negative from volume change.
- For ideal gas, connect internal energy change with temperature change.
Common Mistakes and Memory Tricks
Do not confuse process names. Isothermal has constant temperature, while adiabatic has zero heat exchange. Isochoric has zero work, while isobaric uses W = PΔV. The memory trick is: thermal relates to temperature, adiabatic blocks heat, choric relates to volume space, and baric relates to pressure.
P-V Diagrams
P-V diagrams show pressure on the vertical axis and volume on the horizontal axis. Work done is the area under the process curve.
The isothermal and adiabatic curves both slope downward for expansion, but the adiabatic curve is steeper. This is because during adiabatic expansion the gas cools, so pressure falls more rapidly than in isothermal expansion.
Isothermal Expansion in Piston
Adiabatic Expansion
Isochoric Heating
Isobaric Expansion
Combined P-V Curves
Molecular Interpretation
Isothermal P-V Graph
Adiabatic P-V Graph
Isochoric and Isobaric P-V Graphs
Work Done in Thermodynamic Processes
Work done by gas is the area under the P-V curve. The formula changes with the process path.
Isothermal ideal gas condition. Pressure decreases inversely with volume.
Adiabatic ideal gas condition. Curve is steeper than isothermal.
Work for reversible isothermal ideal gas process.
Work for constant pressure process.
For isochoric process because W = 0.
For ideal gas isothermal process because temperature is constant.
For adiabatic process because there is no heat exchange.
For isochoric process because volume is constant.
Process Comparison
| Process | Constant quantity | Heat exchange | Work done | Internal energy | Formula | P-V graph | Exam note |
|---|---|---|---|---|---|---|---|
| Isothermal | Temperature | Allowed | W = nRT ln(V2/V1) | ΔU = 0 for ideal gas | PV = constant | Rectangular hyperbola | Heat supplied equals work in ideal gas expansion. |
| Adiabatic | Heat exchange zero | Q = 0 | Done at cost of internal energy | Changes with temperature | PVγ = constant | Steeper than isothermal | Rapid or insulated process. |
| Isochoric | Volume | Allowed | W = 0 | ΔU = Q | V constant | Vertical line | Rigid container. |
| Isobaric | Pressure | Allowed | W = PΔV | Depends on temperature change | P constant | Horizontal line | Movable piston under constant load. |
Isothermal vs Adiabatic
Both may appear as downward curves during expansion, but isothermal keeps temperature constant by heat exchange, while adiabatic blocks heat exchange and therefore temperature changes. For the same initial point, the adiabatic expansion curve drops more steeply.
Isochoric vs Isobaric
Isochoric has no work because volume does not change. Isobaric has easy work calculation because pressure is constant. On P-V diagrams, isochoric is vertical and isobaric is horizontal.
If Thermodynamic Processes are not clear and you are looking for a Physics Tutor, contact Kumar Sir.
50 Solved Numericals
Attempt each question first, then open the solution.
Show Solution
Given: n = 1, T = 300 K, V2/V1 = 2.
Formula: W = nRT ln(V2/V1).
Solution: W = 1 × 8.314 × 300 × 0.693 = 1728 J approximately.
Final Answer: Work done = 1.73 × 103 J.
Show Solution
Given: P = 2 × 105 Pa, ΔV = 5 L = 5 × 10-3 m3.
Formula: W = PΔV.
Solution: W = 2 × 105 × 5 × 10-3 = 1000 J.
Final Answer: Work done = 1000 J.
Show Solution
Given: Isochoric process, Q = 600 J.
Formula: W = 0, ΔU = Q.
Solution: At constant volume, no boundary displacement occurs. Therefore W = 0 and ΔU = 600 J.
Final Answer: W = 0, ΔU = 600 J.
Show Solution
Given: Adiabatic process, W = 450 J.
Formula: Q = 0, ΔU = Q - W.
Solution: ΔU = 0 - 450 = -450 J.
Final Answer: Q = 0, ΔU = -450 J.
Show Solution
Given: Ideal gas isothermal process, Q = 900 J.
Formula: ΔU = 0, Q = W.
Solution: Temperature is constant, so internal energy does not change. Therefore W = 900 J.
Final Answer: ΔU = 0, W = 900 J.
Show Solution
Given: P = 1 × 105 Pa, ΔV = -4 L = -4 × 10-3 m3.
Formula: W = PΔV.
Solution: W = 1 × 105 × (-4 × 10-3) = -400 J.
Final Answer: Work by gas = -400 J.
Show Solution
Given: Isochoric process, P proportional to T.
Formula: P1/T1 = P2/T2.
Solution: Since pressure doubles, temperature doubles. T2 = 600 K.
Final Answer: Final temperature = 600 K.
Show Solution
Given: Isothermal process, V2 = 2V1, P1 = 4 atm.
Formula: P1V1 = P2V2.
Solution: P2 = P1V1/2V1 = 2 atm.
Final Answer: Final pressure = 2 atm.
Show Solution
Given: Adiabatic expansion, W = 300 J.
Formula: Q = 0, ΔU = -W.
Solution: ΔU = -300 J. For ideal gas, internal energy depends on temperature, so temperature decreases.
Final Answer: Temperature decreases.
Show Solution
Given: Q = 1200 J, W = 400 J.
Formula: ΔU = Q - W.
Solution: ΔU = 1200 - 400 = 800 J.
Final Answer: Internal energy increases by 800 J.
Show Solution
Given: n = 1, T = 300 K, V2/V1 = 2.
Formula: W = nRT ln(V2/V1).
Solution: W = 1 × 8.314 × 300 × 0.693 = 1728 J approximately.
Final Answer: Work done = 1.73 × 103 J.
Show Solution
Given: P = 2 × 105 Pa, ΔV = 5 L = 5 × 10-3 m3.
Formula: W = PΔV.
Solution: W = 2 × 105 × 5 × 10-3 = 1000 J.
Final Answer: Work done = 1000 J.
Show Solution
Given: Isochoric process, Q = 600 J.
Formula: W = 0, ΔU = Q.
Solution: At constant volume, no boundary displacement occurs. Therefore W = 0 and ΔU = 600 J.
Final Answer: W = 0, ΔU = 600 J.
Show Solution
Given: Adiabatic process, W = 450 J.
Formula: Q = 0, ΔU = Q - W.
Solution: ΔU = 0 - 450 = -450 J.
Final Answer: Q = 0, ΔU = -450 J.
Show Solution
Given: Ideal gas isothermal process, Q = 900 J.
Formula: ΔU = 0, Q = W.
Solution: Temperature is constant, so internal energy does not change. Therefore W = 900 J.
Final Answer: ΔU = 0, W = 900 J.
Show Solution
Given: P = 1 × 105 Pa, ΔV = -4 L = -4 × 10-3 m3.
Formula: W = PΔV.
Solution: W = 1 × 105 × (-4 × 10-3) = -400 J.
Final Answer: Work by gas = -400 J.
Show Solution
Given: Isochoric process, P proportional to T.
Formula: P1/T1 = P2/T2.
Solution: Since pressure doubles, temperature doubles. T2 = 600 K.
Final Answer: Final temperature = 600 K.
Show Solution
Given: Isothermal process, V2 = 2V1, P1 = 4 atm.
Formula: P1V1 = P2V2.
Solution: P2 = P1V1/2V1 = 2 atm.
Final Answer: Final pressure = 2 atm.
Show Solution
Given: Adiabatic expansion, W = 300 J.
Formula: Q = 0, ΔU = -W.
Solution: ΔU = -300 J. For ideal gas, internal energy depends on temperature, so temperature decreases.
Final Answer: Temperature decreases.
Show Solution
Given: Q = 1200 J, W = 400 J.
Formula: ΔU = Q - W.
Solution: ΔU = 1200 - 400 = 800 J.
Final Answer: Internal energy increases by 800 J.
Show Solution
Given: n = 1, T = 300 K, V2/V1 = 2.
Formula: W = nRT ln(V2/V1).
Solution: W = 1 × 8.314 × 300 × 0.693 = 1728 J approximately.
Final Answer: Work done = 1.73 × 103 J.
Show Solution
Given: P = 2 × 105 Pa, ΔV = 5 L = 5 × 10-3 m3.
Formula: W = PΔV.
Solution: W = 2 × 105 × 5 × 10-3 = 1000 J.
Final Answer: Work done = 1000 J.
Show Solution
Given: Isochoric process, Q = 600 J.
Formula: W = 0, ΔU = Q.
Solution: At constant volume, no boundary displacement occurs. Therefore W = 0 and ΔU = 600 J.
Final Answer: W = 0, ΔU = 600 J.
Show Solution
Given: Adiabatic process, W = 450 J.
Formula: Q = 0, ΔU = Q - W.
Solution: ΔU = 0 - 450 = -450 J.
Final Answer: Q = 0, ΔU = -450 J.
Show Solution
Given: Ideal gas isothermal process, Q = 900 J.
Formula: ΔU = 0, Q = W.
Solution: Temperature is constant, so internal energy does not change. Therefore W = 900 J.
Final Answer: ΔU = 0, W = 900 J.
Show Solution
Given: P = 1 × 105 Pa, ΔV = -4 L = -4 × 10-3 m3.
Formula: W = PΔV.
Solution: W = 1 × 105 × (-4 × 10-3) = -400 J.
Final Answer: Work by gas = -400 J.
Show Solution
Given: Isochoric process, P proportional to T.
Formula: P1/T1 = P2/T2.
Solution: Since pressure doubles, temperature doubles. T2 = 600 K.
Final Answer: Final temperature = 600 K.
Show Solution
Given: Isothermal process, V2 = 2V1, P1 = 4 atm.
Formula: P1V1 = P2V2.
Solution: P2 = P1V1/2V1 = 2 atm.
Final Answer: Final pressure = 2 atm.
Show Solution
Given: Adiabatic expansion, W = 300 J.
Formula: Q = 0, ΔU = -W.
Solution: ΔU = -300 J. For ideal gas, internal energy depends on temperature, so temperature decreases.
Final Answer: Temperature decreases.
Show Solution
Given: Q = 1200 J, W = 400 J.
Formula: ΔU = Q - W.
Solution: ΔU = 1200 - 400 = 800 J.
Final Answer: Internal energy increases by 800 J.
Show Solution
Given: n = 1, T = 300 K, V2/V1 = 2.
Formula: W = nRT ln(V2/V1).
Solution: W = 1 × 8.314 × 300 × 0.693 = 1728 J approximately.
Final Answer: Work done = 1.73 × 103 J.
Show Solution
Given: P = 2 × 105 Pa, ΔV = 5 L = 5 × 10-3 m3.
Formula: W = PΔV.
Solution: W = 2 × 105 × 5 × 10-3 = 1000 J.
Final Answer: Work done = 1000 J.
Show Solution
Given: Isochoric process, Q = 600 J.
Formula: W = 0, ΔU = Q.
Solution: At constant volume, no boundary displacement occurs. Therefore W = 0 and ΔU = 600 J.
Final Answer: W = 0, ΔU = 600 J.
Show Solution
Given: Adiabatic process, W = 450 J.
Formula: Q = 0, ΔU = Q - W.
Solution: ΔU = 0 - 450 = -450 J.
Final Answer: Q = 0, ΔU = -450 J.
Show Solution
Given: Ideal gas isothermal process, Q = 900 J.
Formula: ΔU = 0, Q = W.
Solution: Temperature is constant, so internal energy does not change. Therefore W = 900 J.
Final Answer: ΔU = 0, W = 900 J.
Show Solution
Given: P = 1 × 105 Pa, ΔV = -4 L = -4 × 10-3 m3.
Formula: W = PΔV.
Solution: W = 1 × 105 × (-4 × 10-3) = -400 J.
Final Answer: Work by gas = -400 J.
Show Solution
Given: Isochoric process, P proportional to T.
Formula: P1/T1 = P2/T2.
Solution: Since pressure doubles, temperature doubles. T2 = 600 K.
Final Answer: Final temperature = 600 K.
Show Solution
Given: Isothermal process, V2 = 2V1, P1 = 4 atm.
Formula: P1V1 = P2V2.
Solution: P2 = P1V1/2V1 = 2 atm.
Final Answer: Final pressure = 2 atm.
Show Solution
Given: Adiabatic expansion, W = 300 J.
Formula: Q = 0, ΔU = -W.
Solution: ΔU = -300 J. For ideal gas, internal energy depends on temperature, so temperature decreases.
Final Answer: Temperature decreases.
Show Solution
Given: Q = 1200 J, W = 400 J.
Formula: ΔU = Q - W.
Solution: ΔU = 1200 - 400 = 800 J.
Final Answer: Internal energy increases by 800 J.
Show Solution
Given: n = 1, T = 300 K, V2/V1 = 2.
Formula: W = nRT ln(V2/V1).
Solution: W = 1 × 8.314 × 300 × 0.693 = 1728 J approximately.
Final Answer: Work done = 1.73 × 103 J.
Show Solution
Given: P = 2 × 105 Pa, ΔV = 5 L = 5 × 10-3 m3.
Formula: W = PΔV.
Solution: W = 2 × 105 × 5 × 10-3 = 1000 J.
Final Answer: Work done = 1000 J.
Show Solution
Given: Isochoric process, Q = 600 J.
Formula: W = 0, ΔU = Q.
Solution: At constant volume, no boundary displacement occurs. Therefore W = 0 and ΔU = 600 J.
Final Answer: W = 0, ΔU = 600 J.
Show Solution
Given: Adiabatic process, W = 450 J.
Formula: Q = 0, ΔU = Q - W.
Solution: ΔU = 0 - 450 = -450 J.
Final Answer: Q = 0, ΔU = -450 J.
Show Solution
Given: Ideal gas isothermal process, Q = 900 J.
Formula: ΔU = 0, Q = W.
Solution: Temperature is constant, so internal energy does not change. Therefore W = 900 J.
Final Answer: ΔU = 0, W = 900 J.
Show Solution
Given: P = 1 × 105 Pa, ΔV = -4 L = -4 × 10-3 m3.
Formula: W = PΔV.
Solution: W = 1 × 105 × (-4 × 10-3) = -400 J.
Final Answer: Work by gas = -400 J.
Show Solution
Given: Isochoric process, P proportional to T.
Formula: P1/T1 = P2/T2.
Solution: Since pressure doubles, temperature doubles. T2 = 600 K.
Final Answer: Final temperature = 600 K.
Show Solution
Given: Isothermal process, V2 = 2V1, P1 = 4 atm.
Formula: P1V1 = P2V2.
Solution: P2 = P1V1/2V1 = 2 atm.
Final Answer: Final pressure = 2 atm.
Show Solution
Given: Adiabatic expansion, W = 300 J.
Formula: Q = 0, ΔU = -W.
Solution: ΔU = -300 J. For ideal gas, internal energy depends on temperature, so temperature decreases.
Final Answer: Temperature decreases.
Show Solution
Given: Q = 1200 J, W = 400 J.
Formula: ΔU = Q - W.
Solution: ΔU = 1200 - 400 = 800 J.
Final Answer: Internal energy increases by 800 J.
50 PYQs and Exam Questions
Answers are hidden so this works like a real question bank.
Show Answer
Explanation: An isothermal process occurs at constant temperature. For an ideal gas, internal energy remains constant.
Answer: T = constant.
Show Answer
Explanation: An adiabatic process has no heat exchange between system and surroundings.
Answer: Q = 0.
Show Answer
Explanation: Volume remains constant, so boundary displacement is zero.
Answer: W = 0.
Show Answer
Explanation: Pressure remains constant, so work is pressure times volume change.
Answer: W = P(V2 - V1).
Show Answer
Explanation: For ideal gas, internal energy depends only on temperature. Isothermal means temperature constant.
Answer: (A) Isothermal.
Show Answer
Explanation: No heat exchange is the defining condition of adiabatic process.
Answer: (B) Adiabatic.
Show Answer
Explanation: For the same volume increase, pressure falls faster in adiabatic expansion because the gas cools while doing work.
Answer: Temperature changes in adiabatic expansion.
Show Answer
Explanation: Vertical line means volume is constant.
Answer: Isochoric process.
Show Answer
Explanation: Horizontal line means pressure is constant.
Answer: Isobaric process.
Show Answer
Explanation: Internal energy change is zero, so heat supplied equals work done.
Answer: Q = W.
Show Answer
Explanation: No heat enters, so work done by gas comes from internal energy.
Answer: Internal energy decreases.
Show Answer
Explanation: The isothermal curve lies above the adiabatic curve during expansion, so area under it is larger.
Answer: Isothermal work is greater.
Show Answer
Explanation: Average molecular kinetic energy remains constant while heat enters to replace energy leaving as work.
Answer: Molecular average kinetic energy remains constant.
Show Answer
Explanation: For a fixed amount of gas at constant temperature, pressure varies inversely with volume.
Answer: PV = constant.
Show Answer
Explanation: The constant-volume process is called isochoric.
Answer: Isochoric.
Show Answer
Explanation: Work is the area under P-V graph.
Answer: W = ∫PdV.
Show Answer
Explanation: Both are true and the reason correctly explains the assertion.
Answer: Both true; reason is correct.
Show Answer
Explanation: Both are true and the reason correctly explains the assertion.
Answer: Both true; reason is correct.
Show Answer
Explanation: False. Adiabatic means no heat exchange; temperature can change due to work.
Answer: False.
Show Answer
Explanation: True because volume does not change.
Answer: True.
Show Answer
Explanation: Slow expansion allows heat exchange with surroundings to maintain constant temperature.
Answer: To maintain thermal equilibrium and constant T.
Show Answer
Explanation: There is very little time for heat exchange with surroundings.
Answer: Heat transfer is negligible.
Show Answer
Explanation: Using W = nRT ln(V2/V1), work is nRT ln2.
Answer: W = nRT ln2.
Show Answer
Explanation: Rapid compression gives little time for heat loss, so it is nearly adiabatic.
Answer: Adiabatic compression.
Show Answer
Explanation: Rapid adiabatic compression raises air temperature enough to ignite fuel.
Answer: Temperature rises in adiabatic compression.
Show Answer
Explanation: An isothermal process occurs at constant temperature. For an ideal gas, internal energy remains constant.
Answer: T = constant.
Show Answer
Explanation: An adiabatic process has no heat exchange between system and surroundings.
Answer: Q = 0.
Show Answer
Explanation: Volume remains constant, so boundary displacement is zero.
Answer: W = 0.
Show Answer
Explanation: Pressure remains constant, so work is pressure times volume change.
Answer: W = P(V2 - V1).
Show Answer
Explanation: For ideal gas, internal energy depends only on temperature. Isothermal means temperature constant.
Answer: (A) Isothermal.
Show Answer
Explanation: No heat exchange is the defining condition of adiabatic process.
Answer: (B) Adiabatic.
Show Answer
Explanation: For the same volume increase, pressure falls faster in adiabatic expansion because the gas cools while doing work.
Answer: Temperature changes in adiabatic expansion.
Show Answer
Explanation: Vertical line means volume is constant.
Answer: Isochoric process.
Show Answer
Explanation: Horizontal line means pressure is constant.
Answer: Isobaric process.
Show Answer
Explanation: Internal energy change is zero, so heat supplied equals work done.
Answer: Q = W.
Show Answer
Explanation: No heat enters, so work done by gas comes from internal energy.
Answer: Internal energy decreases.
Show Answer
Explanation: The isothermal curve lies above the adiabatic curve during expansion, so area under it is larger.
Answer: Isothermal work is greater.
Show Answer
Explanation: Average molecular kinetic energy remains constant while heat enters to replace energy leaving as work.
Answer: Molecular average kinetic energy remains constant.
Show Answer
Explanation: For a fixed amount of gas at constant temperature, pressure varies inversely with volume.
Answer: PV = constant.
Show Answer
Explanation: The constant-volume process is called isochoric.
Answer: Isochoric.
Show Answer
Explanation: Work is the area under P-V graph.
Answer: W = ∫PdV.
Show Answer
Explanation: Both are true and the reason correctly explains the assertion.
Answer: Both true; reason is correct.
Show Answer
Explanation: Both are true and the reason correctly explains the assertion.
Answer: Both true; reason is correct.
Show Answer
Explanation: False. Adiabatic means no heat exchange; temperature can change due to work.
Answer: False.
Show Answer
Explanation: True because volume does not change.
Answer: True.
Show Answer
Explanation: Slow expansion allows heat exchange with surroundings to maintain constant temperature.
Answer: To maintain thermal equilibrium and constant T.
Show Answer
Explanation: There is very little time for heat exchange with surroundings.
Answer: Heat transfer is negligible.
Show Answer
Explanation: Using W = nRT ln(V2/V1), work is nRT ln2.
Answer: W = nRT ln2.
Show Answer
Explanation: Rapid compression gives little time for heat loss, so it is nearly adiabatic.
Answer: Adiabatic compression.
Show Answer
Explanation: Rapid adiabatic compression raises air temperature enough to ignite fuel.
Answer: Temperature rises in adiabatic compression.
Case Study Practice
Bicycle Pump
Rapid compression traps air and raises its temperature. This is an approximate adiabatic compression.
Diesel Engine
Air is compressed rapidly, temperature rises sharply, and injected fuel ignites without spark plug.
Refrigerator
The working fluid undergoes compression, cooling, expansion and evaporation in a cycle.
Pressure Cooker
Before steam release, volume is nearly fixed and pressure rises with temperature.
Hot Air Balloon
Heating air at nearly atmospheric pressure increases volume and lowers density.
Gas Cylinder
A rigid gas cylinder is close to constant-volume behavior when warmed.
Quick Revision Notes
Important Formula Sheet
- Isothermal: T constant
- Isothermal ideal gas: PV = constant
- Isothermal work: W = nRT ln(V2/V1)
- Adiabatic: Q = 0
- Adiabatic ideal gas: PVγ = constant
- Isochoric: V constant, W = 0
- Isobaric: P constant, W = PΔV
Most Common Mistakes
- Confusing isothermal with adiabatic.
- Forgetting that adiabatic curve is steeper.
- Using PΔV when pressure is not constant.
- Writing W nonzero in isochoric process.
- Thinking Q = 0 means temperature cannot change.
- Forgetting litre to metre cube conversion.
Exam Tips
- Identify the constant quantity first.
- Draw the P-V graph before calculating work.
- For ideal gas isothermal process, write ΔU = 0 immediately.
- For adiabatic process, write Q = 0 immediately.
- For isochoric process, write W = 0 immediately.
- For isobaric process, use rectangular area PΔV.
If Thermodynamic Processes are not clear and you are looking for a Physics Tutor, contact Kumar Sir.
Phone: +91-9958461445 Email: kumarsirphysics@gmail.com
